By Valentine P. Ananikov, Masato Tanaka
Valentine P. Ananikov, Irina P. Beletskaya: Alkyne and alkene insertion into metal-heteroatom and metal-hydrogen bonds – the major levels of hydrofunctionalization process.- Akihiko Ishii* and Norio Nakata: The Mechanism for Transition Metal-Catalyzed Hydrochalcogenation of Unsaturated natural Molecules.- A. L. Reznichenko and Kai C. Hultzsch: Early Transition steel (Group 3-5, Lanthanides and Actinides) and major team steel (Group 1, 2, and thirteen) Catalyzed Hydroamination.- Naoko Nishina and Yoshinori Yamamoto: past due transition steel catalyzed hydroamination.- Sumod A. Pullarkat and Pak-Hing Leung: Chiral steel complicated Promoted uneven Hydrophosphinations.- Masato Tanaka: fresh growth in Transition Metal-Catalyzed Addition Reactions of H-P(O) Compounds with Unsaturated Carbon Linkages.- Christian Bruneau: staff eight metals-catalyzed O-H bond addition to unsaturated molecules.- Giorgio Abbiati, Egle M. Beccalli, Elisabetta Rossi: teams nine and 10 metals-catalyzed O-H bond addition to unsaturated molecules.- Núria Huguet and Antonio M. Echavarren: Gold-Catalyzed O-H Bond Addition to Unsaturated natural Molecules.- Akiya Ogawa: Transition-Metal-Catalyzed S-H and Se-H Bonds Addition to Unsaturated Molecules.
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References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 25 31 37 37 40 43 47 47 1 Introduction Introduction of organoelemento functionalities into organic molecules is an important reaction to prepare useful synthetic intermediates [1–8]. This chapter concerns the mechanism of transition-metal-catalyzed addition of chalcogenol (REH: E ¼ O, S, and Se) to carbon–carbon unsaturated bonds.
Organometallics 17:2510–2523 10. Hashmi AKS, B€uhrle M (2010) Gold-catalyzed addition of X-H bonds to C-C multiple bonds. Aldrichimica Acta 43:27–33 11. Santos LL, Ruiz VR, Sabater MJ, Corma A (2008) Regioselective transformation of alkynes into cyclic acetals and thioacetals with a gold(I) catalyst: comparison with Brønsted acid catalysts. Tetrahedron 64:7902–7909 48 A. Ishii and N. Nakata 12. Qian H, Han X, Widenhoefer RA (2004) Platinum-catalyzed intramolecular hydroalkoxylation of g- and d-hydroxy olefins to form cyclic ethers.
1 Group X Metal-Catalyzed Hydrothiolation and Hydroselenation . . . . . . . . . . 2 Groups III and IV Metal-Catalyzed Hydrothiolation and Hydroalkoxylation . . . . 3 Type II Mechanism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Pd(0) and Pt(0)-Catalyzed Hydroselenation of Alkynes . . . . . . . . . . . . . . . 3 Hybrid Type of Type I and Type II Mechanisms: Rh(I) and Ir(I) Complex-Catalyzed Hydrothiolation .